Paints and varnishes - Practical determination of non-volatile and volatile matter content during application (ISO 22516:2019)

This document specifies a test method for the determination of non-volatile matter of coatings directly after application or after intermediate or final drying. In practice, the determination of volatile matter is applied particularly in regard to water-thinnable coatings which are re-coated with an additional coating material.
Furthermore, the method can be used to compare the efficiency of different application and drying methods.
The content of non-volatile or volatile matter of a product after application is no absolute variable but depends on the application and drying conditions applied during the test. Consequently, applying this method gives only relative values and not the real values for the content of non-volatile matter, due to solvent retention, thermal decomposition and evaporation of low-molecular contents.

Beschichtungsstoffe - Praxisnahe Bestimmung des Gehaltes an nichtflüchtigen und flüchtigen Anteilen während des Beschichtungsprozesses (ISO 22516:2019)

Peintures et vernis - Détermination pratique de la matière non volatile et de la matière volatile pendant l'application (ISO 22516:2019)

Le présent document spécifie une méthode d'essai pour déterminer la matière non volatile d'un revêtement directement après application ou après séchage intermédiaire ou final. Dans la pratique, la détermination de la matière volatile est appliquée en particulier pour les revêtements hydrodiluables auxquels est ajoutée une couche supplémentaire de produit de peinture.
Cette méthode peut également permettre de comparer l'efficacité de différentes méthodes d'application et de séchage.
La teneur en matière non volatile ou volatile d'un produit après application n'est pas une variable absolue, mais dépend des conditions d'application et de séchage utilisées pendant l'essai. Par conséquent, le recours à cette méthode permet d'obtenir uniquement des valeurs relatives et non les valeurs réelles de la teneur en matière non volatile, en raison de la rétention du solvant, de la décomposition thermique et de l'évaporation des constituants de faible masse moléculaire.

Barve in laki - Praktično določevanje nehlapnih in hlapnih snovi pri nanašanju (ISO 22516:2019)

General Information

Status
Published
Public Enquiry End Date
01-Oct-2020
Publication Date
27-Jan-2021
Technical Committee
Current Stage
6060 - National Implementation/Publication (Adopted Project)
Start Date
11-Jan-2021
Due Date
18-Mar-2021
Completion Date
28-Jan-2021

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SLOVENSKI STANDARD
SIST EN ISO 22516:2021
01-marec-2021
Barve in laki - Praktično določevanje nehlapnih in hlapnih snovi pri nanašanju
(ISO 22516:2019)
Paints and varnishes - Practical determination of non-volatile and volatile matter content
during application (ISO 22516:2019)
Beschichtungsstoffe - Praxisnahe Bestimmung des Gehaltes an nichtflüchtigen und
flüchtigen Anteilen während des Beschichtungsprozesses (ISO 22516:2019)
Peintures et vernis - Détermination pratique de la matière non volatile et de la matière
volatile pendant l'application (ISO 22516:2019)
Ta slovenski standard je istoveten z: EN ISO 22516:2020
ICS:
87.040 Barve in laki Paints and varnishes
SIST EN ISO 22516:2021 en,fr,de
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

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SIST EN ISO 22516:2021

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SIST EN ISO 22516:2021


EN ISO 22516
EUROPEAN STANDARD

NORME EUROPÉENNE

December 2020
EUROPÄISCHE NORM
ICS 87.040
English Version

Paints and varnishes - Practical determination of non-
volatile and volatile matter content during application (ISO
22516:2019)
Peintures et vernis - Détermination pratique de la Beschichtungsstoffe - Praxisnahe Bestimmung des
matière non volatile et de la matière volatile pendant Gehaltes an nichtflüchtigen und flüchtigen Anteilen
l'application (ISO 22516:2019) während des Beschichtungsprozesses (ISO
22516:2019)
This European Standard was approved by CEN on 30 November 2020.

CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this
European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references
concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN
member.

This European Standard exists in three official versions (English, French, German). A version in any other language made by
translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management
Centre has the same status as the official versions.

CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway,
Poland, Portugal, Republic of North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and
United Kingdom.





EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION

EUROPÄISCHES KOMITEE FÜR NORMUNG

CEN-CENELEC Management Centre: Rue de la Science 23, B-1040 Brussels
© 2020 CEN All rights of exploitation in any form and by any means reserved Ref. No. EN ISO 22516:2020 E
worldwide for CEN national Members.

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SIST EN ISO 22516:2021
EN ISO 22516:2020 (E)
Contents Page
European foreword . 3

2

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SIST EN ISO 22516:2021
EN ISO 22516:2020 (E)
European foreword
The text of ISO 22516:2019 has been prepared by Technical Committee ISO/TC 35 "Paints and
varnishes” of the International Organization for Standardization (ISO) and has been taken over as
EN ISO 22516:2020 by Technical Committee CEN/TC 139 “Paints and varnishes” the secretariat of
which is held by DIN.
This European Standard shall be given the status of a national standard, either by publication of an
identical text or by endorsement, at the latest by June 2021, and conflicting national standards shall be
withdrawn at the latest by June 2021.
Attention is drawn to the possibility that some of the elements of this document may be the subject of
patent rights. CEN shall not be held responsible for identifying any or all such patent rights.
According to the CEN-CENELEC Internal Regulations, the national standards organizations of the
following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria,
Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland,
Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Republic of
North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and the
United Kingdom.
Endorsement notice
The text of ISO 22516:2019 has been approved by CEN as EN ISO 22516:2020 without any modification.

3

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SIST EN ISO 22516:2021

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SIST EN ISO 22516:2021
INTERNATIONAL ISO
STANDARD 22516
First edition
2019-06
Paints and varnishes — Practical
determination of non-volatile and
volatile matter content during
application
Peintures et vernis — Détermination pratique de la matière non
volatile et de la matière volatile pendant l'application
Reference number
ISO 22516:2019(E)
©
ISO 2019

---------------------- Page: 7 ----------------------
SIST EN ISO 22516:2021
ISO 22516:2019(E)

COPYRIGHT PROTECTED DOCUMENT
© ISO 2019
All rights reserved. Unless otherwise specified, or required in the context of its implementation, no part of this publication may
be reproduced or utilized otherwise in any form or by any means, electronic or mechanical, including photocopying, or posting
on the internet or an intranet, without prior written permission. Permission can be requested from either ISO at the address
below or ISO’s member body in the country of the requester.
ISO copyright office
CP 401 • Ch. de Blandonnet 8
CH-1214 Vernier, Geneva
Phone: +41 22 749 01 11
Fax: +41 22 749 09 47
Email: copyright@iso.org
Website: www.iso.org
Published in Switzerland
ii © ISO 2019 – All rights reserved

---------------------- Page: 8 ----------------------
SIST EN ISO 22516:2021
ISO 22516:2019(E)

Contents Page
Foreword .iv
Introduction .v
1 Scope . 1
2 Normative references . 1
3 Terms and definitions . 1
4 Principle . 2
5 Apparatus and materials. 2
6 Sampling . 3
7 Procedure. 3
7.1 General . 3
7.2 Method A: Determination with aluminium foils . 3
7.3 Method B: Determination with test panels. 4
8 Evaluation . 4
9 Precision . 4
9.1 Repeatability limit (r) . 4
9.2 Reproducibility limit (R) . 5
10 Test report . 5
Annex A (informative) Comments on precision . 6
Bibliography . 9
© ISO 2019 – All rights reserved iii

---------------------- Page: 9 ----------------------
SIST EN ISO 22516:2021
ISO 22516:2019(E)

Foreword
ISO (the International Organization for Standardization) is a worldwide federation of national standards
bodies (ISO member bodies). The work of preparing International Standards is normally carried out
through ISO technical committees. Each member body interested in a subject for which a technical
committee has been established has the right to be represented on that committee. International
organizations, governmental and non-governmental, in liaison with ISO, also take part in the work.
ISO collaborates closely with the International Electrotechnical Commission (IEC) on all matters of
electrotechnical standardization.
The procedures used to develop this document and those intended for its further maintenance are
described in the ISO/IEC Directives, Part 1. In particular, the different approval criteria needed for the
different types of ISO documents should be noted. This document was drafted in accordance with the
editorial rules of the ISO/IEC Directives, Part 2 (see www .iso .org/directives).
Attention is drawn to the possibility that some of the elements of this document may be the subject of
patent rights. ISO shall not be held responsible for identifying any or all such patent rights. Details of
any patent rights identified during the development of the document will be in the Introduction and/or
on the ISO list of patent declarations received (see www .iso .org/patents).
Any trade name used in this document is information given for the convenience of users and does not
constitute an endorsement.
For an explanation of the voluntary nature of standards, the meaning of ISO specific terms and
expressions related to conformity assessment, as well as information about ISO's adherence to the
World Trade Organization (WTO) principles in the Technical Barriers to Trade (TBT), see www .iso
.org/iso/foreword .html.
This document was prepared by Technical Committee ISO/TC 35, Paints and varnishes, Subcommittee
SC 9, General test methods for paints and varnishes.
Any feedback or questions on this document should be directed to the user’s national standards body. A
complete listing of these bodies can be found at www .iso .org/members .html.
iv © ISO 2019 – All rights reserved

---------------------- Page: 10 ----------------------
SIST EN ISO 22516:2021
ISO 22516:2019(E)

Introduction
When applying coatings, the size or the size distribution of the generated drops is of great importance
for the application result. By varying the application parameters, such as spraying energy and the
rate of flow of the coating material as well as the technical properties such as solvent composition and
rheological flow performance, the quality of the application result can be controlled. Also, climatic
conditions during the application (e.g. temperature, relative humidity, and air falling speed) highly
influence the result. By determining the non-volatile matter after application or after intermediate
or final drying, it is possible to characterize the wet or dry application result and, consequently, to
indirectly refer to the generated drop size distribution and the solvent emission during the application.
By means of the calculated volatile matter, the sufficient intermediate drying of the respective coating
is determined before applying an additional coating.
© ISO 2019 – All rights reserved v

---------------------- Page: 11 ----------------------
SIST EN ISO 22516:2021

---------------------- Page: 12 ----------------------
SIST EN ISO 22516:2021
INTERNATIONAL STANDARD ISO 22516:2019(E)
Paints and varnishes — Practical determination of non-
volatile and volatile matter content during application
1 Scope
This document specifies a test method for the determination of non-volatile matter of coatings directly
after application or after intermediate or final drying. In practice, the determination of volatile matter
is applied particularly in regard to water-thinnable coatings which are re-coated with an additional
coating material.
Furthermore, the method can be used to compare the efficiency of different application and drying
methods.
The content of non-vola
...

SLOVENSKI STANDARD
oSIST prEN ISO 22516:2020
01-september-2020
Barve in laki - Praktično določevanje nehlapnih in hlapnih snovi pri nanašanju
(ISO 22516:2019)
Paints and varnishes - Practical determination of non-volatile and volatile matter content
during application (ISO 22516:2019)
Beschichtungsstoffe - Praxisnahe Bestimmung des Gehaltes an nichtflüchtigen und
flüchtigen Anteilen während des Beschichtungsprozesses (ISO 22516:2019)
Peintures et vernis - Détermination pratique de la matière non volatile et de la matière
volatile pendant l'application (ISO 22516:2019)
Ta slovenski standard je istoveten z: prEN ISO 22516
ICS:
87.040 Barve in laki Paints and varnishes
oSIST prEN ISO 22516:2020 en,fr,de
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

---------------------- Page: 1 ----------------------
oSIST prEN ISO 22516:2020

---------------------- Page: 2 ----------------------
oSIST prEN ISO 22516:2020
INTERNATIONAL ISO
STANDARD 22516
First edition
2019-06
Paints and varnishes — Practical
determination of non-volatile and
volatile matter content during
application
Peintures et vernis — Détermination pratique de la matière non
volatile et de la matière volatile pendant l'application
Reference number
ISO 22516:2019(E)
©
ISO 2019

---------------------- Page: 3 ----------------------
oSIST prEN ISO 22516:2020
ISO 22516:2019(E)

COPYRIGHT PROTECTED DOCUMENT
© ISO 2019
All rights reserved. Unless otherwise specified, or required in the context of its implementation, no part of this publication may
be reproduced or utilized otherwise in any form or by any means, electronic or mechanical, including photocopying, or posting
on the internet or an intranet, without prior written permission. Permission can be requested from either ISO at the address
below or ISO’s member body in the country of the requester.
ISO copyright office
CP 401 • Ch. de Blandonnet 8
CH-1214 Vernier, Geneva
Phone: +41 22 749 01 11
Fax: +41 22 749 09 47
Email: copyright@iso.org
Website: www.iso.org
Published in Switzerland
ii © ISO 2019 – All rights reserved

---------------------- Page: 4 ----------------------
oSIST prEN ISO 22516:2020
ISO 22516:2019(E)

Contents Page
Foreword .iv
Introduction .v
1 Scope . 1
2 Normative references . 1
3 Terms and definitions . 1
4 Principle . 2
5 Apparatus and materials. 2
6 Sampling . 3
7 Procedure. 3
7.1 General . 3
7.2 Method A: Determination with aluminium foils . 3
7.3 Method B: Determination with test panels. 4
8 Evaluation . 4
9 Precision . 4
9.1 Repeatability limit (r) . 4
9.2 Reproducibility limit (R) . 5
10 Test report . 5
Annex A (informative) Comments on precision . 6
Bibliography . 9
© ISO 2019 – All rights reserved iii

---------------------- Page: 5 ----------------------
oSIST prEN ISO 22516:2020
ISO 22516:2019(E)

Foreword
ISO (the International Organization for Standardization) is a worldwide federation of national standards
bodies (ISO member bodies). The work of preparing International Standards is normally carried out
through ISO technical committees. Each member body interested in a subject for which a technical
committee has been established has the right to be represented on that committee. International
organizations, governmental and non-governmental, in liaison with ISO, also take part in the work.
ISO collaborates closely with the International Electrotechnical Commission (IEC) on all matters of
electrotechnical standardization.
The procedures used to develop this document and those intended for its further maintenance are
described in the ISO/IEC Directives, Part 1. In particular, the different approval criteria needed for the
different types of ISO documents should be noted. This document was drafted in accordance with the
editorial rules of the ISO/IEC Directives, Part 2 (see www .iso .org/directives).
Attention is drawn to the possibility that some of the elements of this document may be the subject of
patent rights. ISO shall not be held responsible for identifying any or all such patent rights. Details of
any patent rights identified during the development of the document will be in the Introduction and/or
on the ISO list of patent declarations received (see www .iso .org/patents).
Any trade name used in this document is information given for the convenience of users and does not
constitute an endorsement.
For an explanation of the voluntary nature of standards, the meaning of ISO specific terms and
expressions related to conformity assessment, as well as information about ISO's adherence to the
World Trade Organization (WTO) principles in the Technical Barriers to Trade (TBT), see www .iso
.org/iso/foreword .html.
This document was prepared by Technical Committee ISO/TC 35, Paints and varnishes, Subcommittee
SC 9, General test methods for paints and varnishes.
Any feedback or questions on this document should be directed to the user’s national standards body. A
complete listing of these bodies can be found at www .iso .org/members .html.
iv © ISO 2019 – All rights reserved

---------------------- Page: 6 ----------------------
oSIST prEN ISO 22516:2020
ISO 22516:2019(E)

Introduction
When applying coatings, the size or the size distribution of the generated drops is of great importance
for the application result. By varying the application parameters, such as spraying energy and the
rate of flow of the coating material as well as the technical properties such as solvent composition and
rheological flow performance, the quality of the application result can be controlled. Also, climatic
conditions during the application (e.g. temperature, relative humidity, and air falling speed) highly
influence the result. By determining the non-volatile matter after application or after intermediate
or final drying, it is possible to characterize the wet or dry application result and, consequently, to
indirectly refer to the generated drop size distribution and the solvent emission during the application.
By means of the calculated volatile matter, the sufficient intermediate drying of the respective coating
is determined before applying an additional coating.
© ISO 2019 – All rights reserved v

---------------------- Page: 7 ----------------------
oSIST prEN ISO 22516:2020

---------------------- Page: 8 ----------------------
oSIST prEN ISO 22516:2020
INTERNATIONAL STANDARD ISO 22516:2019(E)
Paints and varnishes — Practical determination of non-
volatile and volatile matter content during application
1 Scope
This document specifies a test method for the determination of non-volatile matter of coatings directly
after application or after intermediate or final drying. In practice, the determination of volatile matter
is applied particularly in regard to water-thinnable coatings which are re-coated with an additional
coating material.
Furthermore, the method can be used to compare the efficiency of different application and drying
methods.
The content of non-volatile or volatile matter of a product after application is no absolute variable but
depends on the application and drying conditions applied during the test. Consequently, applying this
method gives only relative values and not the real values for the content of non-volatile matter, due to
solvent retention, thermal decomposition and evaporation of low-molecular contents.
2 Normative references
The following documents are referred to in the text in such a way that some or all of their content
constitutes requirements of this document. For dated references, only the edition cited applies. For
undated references, the latest edition of the referenced document (including any amendments) applies.
ISO 1513, Paints and varnishes — Examination and preparation of test samples
ISO 1514, Paints and varnishes — Standard panels for testing
ISO 4618, Paints and varnishes — Terms and definitions
ISO 15528, Paints, varnishes and raw materials for paints and varnishes — Sampling
3 Terms and definitions
For the purposes of this document, the terms and definitions given in ISO 4618 and the following apply.
ISO and IEC maintain terminological databases for use in standardization at the following addresses:
— ISO Online browsing platform: available at https: //www .iso .org/obp
— IEC Electropedia: available at http: //www .electropedia .org/
3.1
process step
operations and time periods, which have to be successive in regard to the coating method in order to
result in a given coating system.
Note 1 to entry: Depending on the focus several successive operations can be subsumed as one process step.
3.2
non-volatile matter after defined process step
NV
P
residue by mass obtained after the application from the single process steps of examination under
specified conditions of test
© ISO 2019 – All rights reserved 1

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oSIST prEN ISO 22516:2020
ISO 22516:2019(E)

3.3
volatile matter
VM
loss by mass obtained by evaporation under spe
...

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