Textiles and textile products - Determination of certain preservatives, method using liquid chromatography

This document specifies a test method for the determination of the content of the following
preservative agents (bioactive agents):
— 2-phenylphenol (OPP);
— triclosan
in textile products by liquid chromatography.
NOTE The preservative agent 2-phenylphenol (OPP) can also be determined according to EN ISO 17070 and quantified by means of gas chromatography/mass spectroscopy (GC/MS).

Textilien und textile Erzeugnisse - Bestimmung bestimmter Konservierungsmittel, Verfahren mittels Flüssigkeitschromatographie

Dieses Dokument legt ein Prüfverfahren zur Bestimmung des Gehalts der Konservierungsmittel (Biozidprodukte) 2-Phenylphenol (OPP) und Triclosan in textilen Materialien und Artikeln aus textilen Erzeugnissen mittels Flüssigkeitschromatographie fest.

Textiles et produits textiles - Détermination de certains agents de conservation, méthode par chromatographie en phase liquide

Le présent document spécifie une méthode d’essai pour la détermination de la teneur en agents de conservation (produits biocides) 2-phénylphénol (OPP) et triclosan dans les matériaux textiles et articles textiles composés de produits textiles, par chromatographie en phase liquide.

Tekstilije in tekstilni izdelki - Določevanje nekaterih konzervansov, metoda z uporabo tekočinske kromatografije

Ta dokument določa preskusno metodo za določanje vsebnosti naslednjih
konzervansov (bioaktivnih snovi):
– 2-fenilfenol (OPP);
– triklosan
v tekstilnih izdelkih s tekočinsko kromatografijo.
OPOMBA: Konzervans 2-fenilfenol (OPP) lahko določimo tudi v skladu s standardom EN ISO 17070 in ga količinsko določimo s plinsko kromatografijo/masno spektroskopijo (GC/MS).

General Information

Status
Withdrawn
Public Enquiry End Date
01-Apr-2018
Publication Date
11-Aug-2019
Withdrawal Date
15-Aug-2023
Current Stage
9900 - Withdrawal (Adopted Project)
Start Date
27-Jul-2023
Due Date
19-Aug-2023
Completion Date
16-Aug-2023

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SLOVENSKI STANDARD
SIST EN 17134:2019
01-september-2019
Tekstilije in tekstilni izdelki - Določevanje nekaterih konzervansov, metoda z
uporabo tekočinske kromatografije
Textiles and textile products - Determination of certain preservatives, method using liquid
chromatography
Textilien und textile Erzeugnisse - Bestimmung bestimmter Konservierungsmittel,
Verfahren mittels Flüssigkeitschromatographie
Textiles et produits textiles - Détermination de certains agents de conservation, méthode
par chromatographie en phase liquide
Ta slovenski standard je istoveten z: EN 17134:2019
ICS:
59.080.01 Tekstilije na splošno Textiles in general
71.040.50 Fizikalnokemijske analitske Physicochemical methods of
metode analysis
SIST EN 17134:2019 en,fr,de
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

---------------------- Page: 1 ----------------------

SIST EN 17134:2019

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SIST EN 17134:2019


EN 17134
EUROPEAN STANDARD

NORME EUROPÉENNE

July 2019
EUROPÄISCHE NORM
ICS 59.080.01
English Version

Textiles and textile products - Determination of certain
preservatives, method using liquid chromatography
Textiles et produits textiles - Détermination de certains Textilien und textile Erzeugnisse - Bestimmung
agents de conservation, méthode par chromatographie bestimmter Konservierungsmittel, Verfahren mittels
en phase liquide Flüssigkeitschromatographie
This European Standard was approved by CEN on 26 May 2019.

CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this
European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references
concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN
member.

This European Standard exists in three official versions (English, French, German). A version in any other language made by
translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management
Centre has the same status as the official versions.

CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway,
Poland, Portugal, Republic of North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and
United Kingdom.





EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION

EUROPÄISCHES KOMITEE FÜR NORMUNG

CEN-CENELEC Management Centre: Rue de la Science 23, B-1040 Brussels
© 2019 CEN All rights of exploitation in any form and by any means reserved Ref. No. EN 17134:2019 E
worldwide for CEN national Members.

---------------------- Page: 3 ----------------------

SIST EN 17134:2019
EN 17134:2019 (E)
Contents Page
European foreword . 3
Introduction . 4
1 Scope . 5
2 Normative references . 5
3 Terms and definitions . 5
4 Principle . 5
5 Reagents . 5
6 Apparatus . 6
7 Preparation of test specimens . 6
7.1 Sampling . 6
7.2 Specimen preparation . 6
8 Procedure. 6
8.1 Extraction . 6
8.2 Determination with LC . 6
9 Expression of results . 7
10 Test report . 7
Annex A (informative) Example of chromatographic conditions . 8
Bibliography . 9

2

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SIST EN 17134:2019
EN 17134:2019 (E)
European foreword
This document (EN 17134:2019) has been prepared by Technical Committee CEN/TC 248 “Textiles and
textile products”, the secretariat of which is held by BSI.
This European Standard shall be given the status of a national standard, either by publication of an
identical text or by endorsement, at the latest by January 2020, and conflicting national standards shall
be withdrawn at the latest by January 2020.
Attention is drawn to the possibility that some of the elements of this document may be the subject of
patent rights. CEN shall not be held responsible for identifying any or all such patent rights.
This document is adapted from EN ISO 13365 prepared by the Technical Committee CEN/TC 309,
“Footwear”, in collaboration with ISO Technical Committee ISO/TC 216, “Footwear”, in accordance with
the agreement on technical cooperation between ISO and CEN (Vienna Agreement). The adaptation is
based on the extension of the scope to textile products.
According to the CEN-CENELEC Internal Regulations, the national standards organisations of the
following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria,
Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland,
Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Republic of
North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and the
United Kingdom.
3

---------------------- Page: 5 ----------------------

SIST EN 17134:2019
EN 17134:2019 (E)
Introduction
The European Biocidal Product Regulation [2] concerns the placing on the market and use of biocidal
products, which are used to protect humans, animals, materials or articles against harmful organisms,
like pests or bacteria, by the action of the active substances contained in the biocidal product. The
Biocidal Products Regulation (BPR) also sets rules for the use of articles treated with, or intentionally
incorporating, one or more biocidal products.
Article 17 "Making available on the market and use of biocidal products" states that biocidal products
are not to be
...

SLOVENSKI STANDARD
oSIST prEN 17134:2018
01-marec-2018
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VHVWDYLQDKPDWHULDORYWHNVWLOQLKL]GHONRY'RORþHYDQMHQHNDWHULKNRQ]HUYDQVRY
PHWRGD]XSRUDERWHNRþLQVNHNURPDWRJUDILMH
Textiles and textile products - Critical substances potentially present in components of
textile product materials - Determination of certain preservatives, method using liquid
chromatography
Textilien und textile Erzeugnisse - Kritische Stoffe, die potentiell in Bestandteilen von
Materialien textiler Erzeugnisse vorhanden sind - Bestimmung gewisser
Konservierungsmittel, Verfahren unter Verwendung von Flüssigkeitschromatographie
Produits textiles - Substances critiques potentiellement présentes dans les composants
des produits textiles - Méthodes d'essai pour déterminer quantitativement la teneur en
agents de conservation (TCMTB, PCMC, OPP, OIT) par chromatographie liquide
Ta slovenski standard je istoveten z: prEN 17134
ICS:
59.080.01 Tekstilije na splošno Textiles in general
71.040.50 Fizikalnokemijske analitske Physicochemical methods of
metode analysis
oSIST prEN 17134:2018 en
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

---------------------- Page: 1 ----------------------
oSIST prEN 17134:2018

---------------------- Page: 2 ----------------------
oSIST prEN 17134:2018


DRAFT
EUROPEAN STANDARD
prEN 17134
NORME EUROPÉENNE

EUROPÄISCHE NORM

February 2018
ICS 59.080.01
English Version

Textiles and textile products - Critical substances
potentially present in components of textile product
materials - Determination of certain preservatives, method
using liquid chromatography
Produits textiles - Substances critiques potentiellement Textilien und textile Erzeugnisse - Kritische Stoffe, die
présentes dans les composants des produits textiles - potentiell in Bestandteilen von Materialien textiler
Méthodes d'essai pour déterminer quantitativement la Erzeugnisse vorhanden sind - Bestimmung gewisser
teneur en agents de conservation (TCMTB, PCMC, OPP, Konservierungsmittel, Verfahren unter Verwendung
OIT) par chromatographie liquide von Flüssigkeitschromatographie
This draft European Standard is submitted to CEN members for enquiry. It has been drawn up by the Technical Committee
CEN/TC 248.

If this draft becomes a European Standard, CEN members are bound to comply with the CEN/CENELEC Internal Regulations
which stipulate the conditions for giving this European Standard the status of a national standard without any alteration.

This draft European Standard was established by CEN in three official versions (English, French, German). A version in any other
language made by translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC
Management Centre has the same status as the official versions.

CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania,
Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland,
Turkey and United Kingdom.

Recipients of this draft are invited to submit, with their comments, notification of any relevant patent rights of which they are
aware and to provide supporting documentation.

Warning : This document is not a European Standard. It is distributed for review and comments. It is subject to change without
notice and shall not be referred to as a European Standard.


EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION

EUROPÄISCHES KOMITEE FÜR NORMUNG

CEN-CENELEC Management Centre: Rue de la Science 23, B-1040 Brussels
© 2018 CEN All rights of exploitation in any form and by any means reserved Ref. No. prEN 17134:2018 E
worldwide for CEN national Members.

---------------------- Page: 3 ----------------------
oSIST prEN 17134:2018
prEN 17134:2018 (E)
Contents
Page
European foreword . 3
1 Scope . 4
2 Normative references . 4
3 Terms and definitions . 4
4 Principle . 4
5 Reagents . 4
6 Apparatus and materials . 5
7 Procedure . 5
8 Calculation . 6
9 Test report . 6
Annex A (informative) Example of chromatographic conditions . 7
Bibliography . 8
2

---------------------- Page: 4 ----------------------
oSIST prEN 17134:2018
prEN 17134:2018 (E)
European foreword
This document (prEN 17134:2018) has been prepared by Technical Committee CEN/TC 248 “Textiles
and textile products”, the secretariat of which is held by BSI.
This document is currently submitted to the CEN Enquiry.
This document is adapted from EN ISO 13365 prepared by the Technical Committee CEN/TC 309,
"Footwear", in collaboration with ISO Technical Committee ISO/TC 216, "Footwear", in accordance with
the agreement on technical cooperation between ISO and CEN (Vienna Agreement). The adaptation is
based on the extension of the scope to textile products.
3

---------------------- Page: 5 ----------------------
oSIST prEN 17134:2018
prEN 17134:2018 (E)
1 Scope
This document specifies a test method for the determination of the content of the following
preservative age
...

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